Vanadium nitride

Vanadium nitride
Names
	IUPAC name Vanadium nitride
	Other names Vanadium(III) nitride
Identifiers
CAS Number	24646-85-3 ;
ECHA InfoCard	100.042.151
EC Number	246-382-4;
PubChem CID	90570;
	InChI InChI=1S/N.V Key: SKKMWRVAJNPLFY-UHFFFAOYSA-N;
Properties
Chemical formula	VN
Molar mass	64.9482 g/mol
Appearance	black powder
Density	6.13 g/cm3
Melting point	2,050 °C (3,720 °F; 2,320 K)
Structure
Crystal structure	cubic, cF8
Space group	Fm3m, No. 225
Hazards
GHS pictograms
GHS Signal word	Warning
GHS hazard statements	H302, H312, H332
GHS precautionary statements	P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P501
Flash point	Non-flammable
Related compounds
Other anions	vanadium(III) oxide, vanadium carbide
Other cations	titanium nitride, chromium(III) nitride, niobium nitride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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	Infobox references

Vanadium nitride, VN, is a chemical compound of vanadium and nitrogen.

Vanadium nitride is formed during the nitriding of steel and increases wear resistance.[1] Another phase, V₂N, also referred to as vanadium nitride, can be formed along with VN during nitriding.[2] VN has a cubic, rock-salt structure. There is also a low-temperature form, which contains V₄ clusters.[3] The low-temperature phase results from a dynamic instability, when the energy of vibrational modes in the high-temperature NaCl-structure phase, are reduced below zero.[4]

It is a strong-coupled superconductor.[5] Nanocrystalline vanadium nitride has been claimed to have potential for use in supercapacitors.[6] The properties of vanadium nitride depend sensitively on the stoichiometry of the material.[7]

References

Munozriofano, R; Casteletti, L; Nascente, P (2006). "Study of the wear behavior of ion nitrided steels with different vanadium contents". Surface and Coatings Technology. 200 (20–21): 6101. doi:10.1016/j.surfcoat.2005.09.026.
Thermo reactive diffusion vanadium nitride coatings on AISI 1020 steel U.Sen Key Engineering Materials vols 264-268 (2004),577
Kubel, F.; Lengauer, W.; Yvon, K.; Junod, A. (1988). "Structural phase transition at 205 K in stoichiometric vanadium nitride". Physical Review B. 38 (18): 12908. doi:10.1103/PhysRevB.38.12908.
A. B. Mei; O. Hellman; N. Wireklint; C. M. Schlepütz; D. G. Sangiovanni; B. Alling; A. Rockett; L. Hultman; I. Petrov & J. E. Greene (2015). "Dynamic and structural stability of cubic vanadium nitride". Physical Review B. 91 (5): 054101. doi:10.1103/PhysRevB.91.054101.
Zhao, B. R.; Chen, L.; Luo, H. L.; Mullin, D. P. (1984). "Superconducting and normal-state properties of vanadium nitride". Physical Review B. 29 (11): 6198. doi:10.1103/PhysRevB.29.6198.
Choi, D.; Blomgren, G. E.; Kumta, P. N. (2006). "Fast and Reversible Surface Redox Reaction in Nanocrystalline Vanadium Nitride Supercapacitors". Advanced Materials. 18 (9): 1178. doi:10.1002/adma.200502471.
Mei, A. B.; Tuteja, M.; Sangiovanni, D. G.; Haasch, R. T.; Rockett, A.; Hultman, L.; Petrov, I.; Greene, J. E. (2016-08-25). "Growth, nanostructure, and optical properties of epitaxial VNx/MgO(001) (0.80 ≤ x ≤ 1.00) layers deposited by reactive magnetron sputtering". Journal of Materials Chemistry C. 4 (34): 7924–7938. doi:10.1039/C6TC02289H. ISSN 2050-7534.

NH₃
N₂H₄

He(N₂)₁₁

Li₃N

Be₃N₂

BN

β-C₃N₄
g-C₃N₄
C_xN_y

N₂

N_xO_y

NF₃

Ne

Na₃N

Mg₃N₂

AlN

Si₃N₄

PN
P₃N₅

S_xN_y
SN
S₄N₄

NCl₃

Ar

K

Ca₃N₂

ScN

TiN

VN

CrN
Cr₂N

Mn_xN_y

Fe_xN_y

CoN

Ni₃N

CuN

Zn₃N₂

GaN

Ge₃N₄

As

Se

NBr₃

Kr

Rb

Sr₃N₂

YN

ZrN

NbN

β-Mo₂N

Tc

Ru

Rh

PdN

Ag₃N

CdN

InN

Sn

Sb

Te

NI₃

Xe

Cs

Ba₃N₂

Hf₃N₄

TaN

WN

Re

Os

Ir

Pt

Au

Hg₃N₂

TlN

Pb

BiN

Po

At

Rn

Fr

Ra₃N₂

Rf

Db

Sg

Bh

Hs

Mt

Ds

Rg

Cn

Nh

Fl

Mc

Lv

Ts

Og

↓

La

CeN

Pr

Nd

Pm

Sm

Eu

GdN

Tb

Dy

Ho

Er

Tm

Yb

Lu

Ac

Th

Pa

UN

Np

Pu

Am

Cm

Bk

Cf

Es

Fm

Md

No

Lr

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[1] Munozriofano, R; Casteletti, L; Nascente, P (2006). "Study of the wear behavior of ion nitrided steels with different vanadium contents". Surface and Coatings Technology. 200 (20–21): 6101. doi:10.1016/j.surfcoat.2005.09.026.

[2] Thermo reactive diffusion vanadium nitride coatings on AISI 1020 steel U.Sen Key Engineering Materials vols 264-268 (2004),577

[3] Kubel, F.; Lengauer, W.; Yvon, K.; Junod, A. (1988). "Structural phase transition at 205 K in stoichiometric vanadium nitride". Physical Review B. 38 (18): 12908. doi:10.1103/PhysRevB.38.12908.

[4] A. B. Mei; O. Hellman; N. Wireklint; C. M. Schlepütz; D. G. Sangiovanni; B. Alling; A. Rockett; L. Hultman; I. Petrov & J. E. Greene (2015). "Dynamic and structural stability of cubic vanadium nitride". Physical Review B. 91 (5): 054101. doi:10.1103/PhysRevB.91.054101.

[5] Zhao, B. R.; Chen, L.; Luo, H. L.; Mullin, D. P. (1984). "Superconducting and normal-state properties of vanadium nitride". Physical Review B. 29 (11): 6198. doi:10.1103/PhysRevB.29.6198.

[6] Choi, D.; Blomgren, G. E.; Kumta, P. N. (2006). "Fast and Reversible Surface Redox Reaction in Nanocrystalline Vanadium Nitride Supercapacitors". Advanced Materials. 18 (9): 1178. doi:10.1002/adma.200502471.

[7] Mei, A. B.; Tuteja, M.; Sangiovanni, D. G.; Haasch, R. T.; Rockett, A.; Hultman, L.; Petrov, I.; Greene, J. E. (2016-08-25). "Growth, nanostructure, and optical properties of epitaxial VNx/MgO(001) (0.80 ≤ x ≤ 1.00) layers deposited by reactive magnetron sputtering". Journal of Materials Chemistry C. 4 (34): 7924–7938. doi:10.1039/C6TC02289H. ISSN 2050-7534.