Tris(dimethylamino)aluminium dimer

Tris(dimethylamino)aluminium dimer
Names
	IUPAC name N-[bis(dimethylamino)alumanyl]-N-methylmethanamine
Identifiers
CAS Number	32093-39-3 ;
3D model (JSmol)	Interactive image;
ChemSpider	21170557;
ECHA InfoCard	100.154.691
EC Number	626-275-2;
PubChem CID	16688802;
CompTox Dashboard (EPA)	DTXSID60586931;
	InChI InChI=1S/6C2H6N.2Al/c61-3-2;;/h61-2H3;;/q6-1;2+3 Key: JGZUJELGSMSOID-UHFFFAOYSA-N;
	SMILES CN(C)[Al](N(C)C)N(C)C.CN(C)[Al](N(C)C)N(C)C;
Properties
Chemical formula	C12H36Al2N6
Molar mass	318.425 g·mol−1
Appearance	Colorless solid
Density	0.865 g/cm3
Melting point	82-84 °C
Boiling point	90 °C
Hazards[1]
Main hazards	Flammable, Corrosive
GHS pictograms
GHS Signal word	Danger
GHS hazard statements	H260, H314, H318
GHS precautionary statements	P223, P231+232, P260, P264, P280, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P321, P335+334, P363, P370+378, P402+404, P405, P501
Flash point	21.1 °C
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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	Infobox references

Tris(dimethylamino)aluminium dimer, formally bis(μ-dimethylamino)tetrakis(dimethylamino)dialuminium, is an amide complex of aluminium. This compound may be used as a precursor to other aluminium complexes.

Commercially available, this compound may be prepared from lithium dimethylamide and aluminium trichloride.[2]

References

"Tris(dimethylamido)aluminum(III)". American Elements. Retrieved August 21, 2019.
Waggoner, K.M.; Olmstead, M.M.; Power, P.P. (1990). "Structural and spectroscopic characterization of the compounds [Al(NMe2)3]2, [Ga(NMe2)3]2, [(Me2N)2Al{μ-N(H)1-Ad}]2 (1-Ad = 1-adamantanyl) and [{Me(μ-NPh2)Al}2NPh(μ-C6H4)]". Polyhedron. 9 (2–3): 257–263. doi:10.1016/S0277-5387(00)80578-1.

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[1] "Tris(dimethylamido)aluminum(III)". American Elements. Retrieved August 21, 2019.

[2] Waggoner, K.M.; Olmstead, M.M.; Power, P.P. (1990). "Structural and spectroscopic characterization of the compounds [Al(NMe2)3]2, [Ga(NMe2)3]2, [(Me2N)2Al{μ-N(H)1-Ad}]2 (1-Ad = 1-adamantanyl) and [{Me(μ-NPh2)Al}2NPh(μ-C6H4)]". Polyhedron. 9 (2–3): 257–263. doi:10.1016/S0277-5387(00)80578-1.