Sinapoylglucose—sinapoylglucose O-sinapoyltransferase

In enzymology, a sinapoylglucose---sinapoylglucose O-sinapoyltransferase (EC 2.3.1.103) is an enzyme that catalyzes the chemical reaction

2 1-O-sinapoyl beta-D-glucoside D-glucose + 1,2-bis-O-sinapoyl beta-D-glucoside
sinapoylglucose-sinapoylglucose O-sinapoyltransferase
Identifiers
EC number2.3.1.103
CAS number103537-11-7
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
Gene OntologyAmiGO / QuickGO

Hence, this enzyme has one substrate, 1-O-sinapoyl beta-D-glucoside, and two products, D-glucose and 1,2-bis-O-sinapoyl beta-D-glucoside.

This enzyme belongs to the family of transferases, specifically those acyltransferases transferring groups other than aminoacyl groups. The systematic name of this enzyme class is 1-O-(4-hydroxy-3,5-dimethoxycinnamoyl)-beta-D-glucoside:1-O-(4-hydro xy-3,5-dimethoxycinnamoyl-beta-D-glucoside 1-O-sinapoyltransferase. Other names in common use include hydroxycinnamoylglucose-hydroxycinnamoylglucose, hydroxycinnamoyltransferase, 1-(hydroxycinnamoyl)-glucose:1-(hydroxycinnamoyl)-glucose, and hydroxycinnamoyltransferase.

References

    • Dahlbender B, Strack D (1986). "Purification and properties of 1-(hydroxycinnamoyl)-glucose-1-(hydroxycinnamoyl)-glucose hydroxycinnamoyl-transferase from radish seedlings". Phytochemistry. 25: 1043–1046. doi:10.1016/S0031-9422(00)81550-2.


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