Rapidcreekite

Rapidcreekite is a rare mineral with formula Ca₂(SO₄)(CO₃)·4H₂O. The mineral is white to colorless and occurs as groupings of acicular (needle-shaped) crystals. It was discovered in 1983 in northern Yukon, Canada, and described in 1986. Rapidcreekite is structurally and compositionally similar to gypsum.

Rapidcreekite
Rapidcreekite from the Rapid Creek area, Yukon, Canada
General
Category	Sulfate minerals Carbonate minerals
Formula (repeating unit)	Ca2(SO4)(CO3)·4H2O
Strunz classification	7.DG.20[1]
Dana classification	32.2.1.1[1]
Crystal system	Orthorhombic
Crystal class	Dipyramidal (mmm) H-M symbol: (2/m 2/m 2/m)
Space group	Pcnb
Unit cell	a = 15.517(2) Å b = 19.226(3) Å c = 6.1646(8) Å; Z = 8
Identification
Color	White to colorless
Crystal habit	Elongated, flattened to acicular crystals in radiating sprays or crust forming
Cleavage	Perfect on {010} Good on {100}
Fracture	Splintery
Tenacity	Brittle
Mohs scale hardness	2
Luster	Vitreous
Streak	White
Diaphaneity	Transparent
Specific gravity	2.239 (calculated)
Optical properties	Biaxial (+)
Refractive index	nα = 1.516 nβ = 1.518 nγ = 1.531[1]
Birefringence	δ = 0.015[1]
2V angle	45° (measured)
Dispersion	None[1]
Ultraviolet fluorescence	Non-fluorescent[2]
Solubility	Dissolves slowly in 10% HCl[3]
References	[4]

Description

White crystals of rapidcreekite with quartz from the Rapid Creek area

Rapidcreekite is transparent and white to colorless.[4] The mineral occurs as isolated clusters or pervasive crusts of radiating sprays of acicular crystals up to 3 mm (0.12 in) in length.[2][4]

Structure

In the structure of rapidcreekite, there are two distinct calcium sites coordinated by six oxygen anions and two H₂O groups arranged as a square antiprism. The sulfur site is tetrahedrally coordinated by oxygen anions and the carbon site is coordinated by a triangle of oxygen anions. The structural unit of rapidcreekite is a sheet that consists of edge-sharing CaΦ₈ polyhedra (Φ, unspecified species: O or OH) cross-linked by carbonate and sulfate groups. Sheets are held together by weakening hydrogen bonds, accounting for the perfect cleavage along {100}.[5]

The structure and composition of rapidcreekite is similar to that of gypsum. If half of the sulfate groups in gypsum were replaced by carbonate, the formula of rapidcreekite is obtained.[6] If gypsum were transformed by twinning along alternate rows of sulfate groups and the resultant triangles of oxygen along the boundary occupied by carbon, the structure of rapidcreekite would result.[7]

History

Rapidcreekite was first encountered in 1983 in a tributary of Rapid Creek unofficially known as Crosscut Creek at 68°33′45″N 136°47′30″W in northern Yukon.[8] The mineral was named rapidcreekite for the general area in which it was found.[2] The mineral and name were approved by the IMA Commission on New Minerals and Mineral Names (IMA1984-035).[1][2] Rapidcreekite was described in 1986 in the journal Canadian Mineralogist.[8]

The holotype specimen, which consists of a few grams of rapidcreekite on a matrix, is held in the National Mineral Collection of the Geological Survey of Canada in Ottawa. Other specimens are held there and in the National Museum of Natural Sciences in Ottawa.[2]

Occurrence

Rapidcreekite occurs in association with aragonite, gypsum, and kulanite.[4] It has been found in Canada, Germany, Norway, and Romania.[1] The rare mineral occurs as a secondary phase that formed along the surfaces of joints and bedding planes in a quartz-rich sideritic formation.[4][8] In the Rapid Creek area, the formation occurred in Albian ironstones and shales.[5][8]

References

1. "Rapidcreekite". Mindat. Retrieved August 6, 2012.
2. Roberts et al. 1986, p. 52
3. Roberts et al. 1986, p. 53
4. Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Rapidcreekite" (PDF). Handbook of Mineralogy. Chantilly, VA: Mineralogical Society of America.
5. Cooper & Hawthorne 1996, p. 99
6. Cooper & Hawthorne 1996, p. 103
7. Cooper & Hawthorne 1996, p. 104
8. Roberts et al. 1986, p. 51

Bibliography

• Cooper, Mark A.; Hawthorne, Frank C. (Feb 1996). "The crystal structure of rapidcreekite, Ca₂(SO₄)(CO₃)(H₂O)₄, and its relation to the structure of gypsum" (PDF). Canadian Mineralogist. 34 (1): 99–106.CS1 maint: ref=harv (link)
• Roberts, Andrew C.; Ansell, H. Gary; Jonasson, Ian R.; Grice, Joel D.; Ramik, Robert A. (March 1986). "Rapidcreekite, a new hydrated calcium sulfate-carbonate from the Rapid Creek area, Yukon Territory" (PDF). Canadian Mineralogist. 24 (1): 51–54.CS1 maint: ref=harv (link)

External links

Media related to rapidcreekite at Wikimedia Commons