Holger Braunschweig

Holger Braunschweig, ML FRSC, is Head and Chair of Inorganic Chemistry at the Julius-Maximilians-University of Würzburg in Würzburg, Germany. He is best known for founding the field of transition metal-boron multiple bonding (transition metal borylenes),[1][2][3][4] the synthesis of the first stable compounds containing boron-boron[5] and boron-oxygen[6] triple bonds, the isolation of the first non-carbon/nitrogen main-group dicarbonyl,[7] and the first fixation of dinitrogen at an element of the p-block of the periodic table.[8] By modifying a strategy pioneered by Prof. Gregory Robinson of the University of Georgia, Braunschweig also discovered the first rational and high-yield synthesis of neutral compounds containing boron-boron double bonds (diborenes).[5][9][10] In 2016 Braunschweig isolated the first compounds of beryllium in the oxidation state of zero.[11]

Holger Braunschweig
Born1961
Germany
NationalityGerman
Alma materRWTH Aachen University
Known forOrganoboron chemistry, Borylene Chemistry, Diborynes, Diborenes
Awards2009 DFG Gottfried Wilhelm Leibniz Prize, 2014 RSC Main Group Award, 2016 GDCh Alfred Stock Memorial Prize.
Scientific career
FieldsChemistry, Inorganic Chemistry, Organometallic Chemistry, Main-Group Chemistry, Organoboron chemistry
InstitutionsUniversity of Würzburg
Websitehttps://www.braunschweiggroup.de/
Braunschweig's 2018 dinitrogen activation with a transient borylene species

Education and research career

Braunschweig obtained his Ph.D. and Habilitation from RWTH Aachen with P. Paetzold and worked as a postdoctoral researcher with Michael F. Lappert, FRS, at the University of Sussex, Brighton. After two years at Imperial College London as Senior Lecturer and Reader he took up a Chair of Inorganic Chemistry at the Julius-Maximilians-University of Würzburg in 2002, and is now also the founding director of the Institute for Sustainable Chemistry & Catalysis with Boron (ICB).

Professional achievements

In 2009 Braunschweig was awarded the Gottfried Wilhelm Leibniz Prize of the German Research Foundation (DFG) – the highest German-based research prize. He was also awarded the 2014 RSC Main Group Award and the 2016 Alfred Stock Memorial Prize of the German Society of Chemists. He is a Fellow of the Royal Society of Chemistry, a member of the German National Academy of Science (Leopoldina), the Bavarian Academy of Sciences and Humanities, and the North Rhine-Westphalian Academy of Sciences, Humanities and the Arts.

References
  1. Braunschweig, Holger; Wagner, Trixie (1995-04-13). "Synthesis and Structure of the First Transition Metal Borylene Complexes". Angewandte Chemie International Edition in English. 34 (7): 825–826. doi:10.1002/anie.199508251. ISSN 1521-3773.
  2. Braunschweig, Holger; Kollann, Carsten; Englert, Ulli (1998-12-04). "Synthesis and Structure of the First Terminal Borylene Complexes". Angewandte Chemie International Edition. 37 (22): 3179–3180. doi:10.1002/(sici)1521-3773(19981204)37:22<3179::aid-anie3179>3.0.co;2-z. ISSN 1521-3773. PMID 29711330.
  3. Braunschweig, Holger; Dewhurst, Rian D.; Schneider, Achim (2010-07-14). "Electron-Precise Coordination Modes of Boron-Centered Ligands". Chemical Reviews. 110 (7): 3924–3957. doi:10.1021/cr900333n. ISSN 0009-2665. PMID 20235583.
  4. Braunschweig, Holger; Dewhurst, Rian D.; Gessner, Viktoria H. (2013-03-25). "Transition metal borylene complexes". Chemical Society Reviews. 42 (8): 3197–208. doi:10.1039/c3cs35510a. ISSN 1460-4744. PMID 23403460.
  5. Braunschweig, Holger; Dewhurst, Rian D.; Hammond, Kai; Mies, Jan; Radacki, Krzysztof; Vargas, Alfredo (2012-06-15). "Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond". Science. 336 (6087): 1420–1422. Bibcode:2012Sci...336.1420B. doi:10.1126/science.1221138. ISSN 0036-8075. PMID 22700924. S2CID 206540959.
  6. Braunschweig, Holger; Radacki, Krzysztof; Schneider, Achim (2010-04-16). "Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum". Science. 328 (5976): 345–347. Bibcode:2010Sci...328..345B. doi:10.1126/science.1186028. ISSN 0036-8075. PMID 20395506. S2CID 206525030.
  7. Braunschweig, Holger; Dewhurst, Rian D.; Hupp, Florian; Nutz, Marco; Radacki, Krzysztof; Tate, Christopher W.; Vargas, Alfredo; Ye, Qing (2015). "Multiple complexation of CO and related ligands to a main-group element". Nature. 522 (7556): 327–330. Bibcode:2015Natur.522..327B. doi:10.1038/nature14489. PMID 26085273. S2CID 4454142.
  8. Légaré, Marc-André; Bélanger-Chabot, Guillaume; Dewhurst, Rian D.; Welz, Eileen; Krummenacher, Ivo; Engels, Bernd; Braunschweig, Holger (2018-02-23). "Nitrogen fixation and reduction at boron". Science. 359 (6378): 896–900. Bibcode:2018Sci...359..896L. doi:10.1126/science.aaq1684. ISSN 0036-8075. PMID 29472479.
  9. Braunschweig, Holger; Dewhurst, Rian D. (2013-03-25). "Single, Double, Triple Bonds and Chains: The Formation of Electron-Precise B-B Bonds". Angewandte Chemie International Edition. 52 (13): 3574–3583. doi:10.1002/anie.201208189. ISSN 1521-3773. PMID 23362015.
  10. Arrowsmith, Merle; Braunschweig, Holger; Stennett, Tom E. (2017-01-02). "Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds". Angewandte Chemie International Edition. 56 (1): 96–115. doi:10.1002/anie.201610072. ISSN 1521-3773. PMID 27860056.
  11. Arrowsmith, Merle; Braunschweig, Holger; Celik, Mehmet Ali; Dellermann, Theresa; Dewhurst, Rian D.; Ewing, William C.; Hammond, Kai; Kramer, Thomas; Krummenacher, Ivo (2016). "Neutral zero-valent s-block complexes with strong multiple bonding". Nature Chemistry. 8 (9): 890–894. Bibcode:2016NatCh...8..890A. doi:10.1038/nchem.2542. PMID 27334631.
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