Hill limit (solid-state)

In solid-state physics, the Hill limit is a critical distance defined in a lattice of actinide or rare-earth atoms.[1] These atoms own partially filled ${\displaystyle 4f}$ or ${\displaystyle 5f}$ levels in their valence shell and are therefore responsible for the main interaction between each atom and its environment. In this context, the hill limit ${\displaystyle r_{H}}$ is defined as twice the radius of the ${\displaystyle f}$-orbital.[2] Therefore, if two atoms of the lattice are separate by a distance greater than the Hill limit, the overlap of their ${\displaystyle f}$-orbital becomes negligible. A direct consequence is the absence of hopping for the f electrons, ie their localization on the ion sites of the lattice.

Localized f electrons lead to paramagnetic materials since the remaining unpaired spins are stuck in their orbitals. However, when the rare-earth lattice (or a single atom) is embedded in a metallic one (intermetallic compound), interactions with the conduction band allow the f electrons to move through the lattice even for interatomic distances above the Hill limit.

See also

• Anderson impurity model

References

1. Hill, H. H. The Early Actinides: the Periodic System’s f Electron Transition Metal Series, in Plutonium 1970 and Other Actinides (AIME, New York, 1970)
2. Liu, Min; Xu, Yuanji; Hu, Danqing; Fu, Zhaoming; Tong, Ninghua; Chen, Xiangrong; Cheng, Jinguang; Xie, Wenhui; Yang, Yi-feng (2017). "Symmetry-enforced heavy-fermion physics in the quadruple-perovskite CaCu3Ir4O12". arXiv:1705.00846v1. Cite journal requires |journal= (help)