Fluoroanion

A fluoroanion is an anion that contains an element and fluorine atoms. They are also known as complex fluorides. They can occur in salts, or in solution, but not as pure acids. They often contain elements in higher oxidation states. They mostly can be considered as fluorometalates which are a subclass of halometalates.

The following is a list of fluoroanions in atomic number order.

  • trifluoroberyllate
  • tetrafluoroberyllate
  • tetrafluoroborate
  • magnesium tetrafluoride
  • tetrafluoroaluminate
  • hexafluoroaluminate
  • hexafluorosilicate
  • hexafluorophosphate
  • Sulfur trifluoride anion
  • pentafluorosulfate aka pentafluorosulfite or Sulfur pentafluoride ion
  • sulfur pentafluoride anion
  • tetrafluorochlorate
  • hexafluorotitanate
  • hexafluorovanadate(III)
  • hexafluorovanadate(IV)
  • hexafluorovanadate(V)
  • trifluoromanganate MnF−
    3
  • hexafluoromanganate(III)
  • hexafluoromanganate(IV)
  • heptafluoromanganate IV
  • Tetrafluoroferrate 1− and 2−
  • hexafluoroferrate 4− and 3−
  • tetrafluorocobaltate II
  • Hexafluorocobaltate III and IV[1]
  • Heptafluorocobaltate IV[1]
  • Tetrafluoronickelate
  • Hexafluoronickelate II, III and IV
  • hexafluorocuprate
  • tetrafluorozincate
  • Hexafluorogallate
  • hexafluorogermanate
  • hexafluoroarsenate
  • tetrafluorobromate
  • hexafluorobromate
  • pentafluorozirconate ZrF−
    5
  • hexafluorozirconate
  • octafluorozirconate ZrF4−
    8
  • hexafluoroniobate
  • heptafluoroniobate
  • octafluoromolybdate MoF2−
    8
  • tetrafluoropalladate
  • hexafluororhodate
  • hexafluororuthenate(IV)
  • hexafluororuthenate(V)
  • hexafluoroindate
  • hexafluorostannate
  • fluoroantimonate
  • hexafluoroiodate 1−
  • octafluoroxenate
  • tetrafluorolanthanate LaF−
    4
  • pentafluorocerate IV
  • Hexafluorocerate IV[2]
  • Heptafluorocerate IV[2]
  • octafluorocerate IV[2]
  • pentafluorohafnate
  • hexafluorohafnate
  • heptafluorotantalate TaF−
    7
  • octafluorotantalate
  • heptafluorotungstate
  • octafluorotungstate WF2−
    8
  • octafluororhenate
  • hexafluoroplatinate
  • tetrafluoroaurate AuF−
    4
  • hexafluoroaurate AuF−
    6
  • hexafluorothallate(III)
  • tetrafluorobismuthate BiF−
    4

References
  1. Klemm, W.; Brandt, W.; Hoppe, R. (March 1961). "Über Fluorocobaltate(III) und -(IV) und Fluoroniccolate(III)". Zeitschrift für anorganische und allgemeine Chemie. 308 (1–6): 179–189. doi:10.1002/zaac.19613080119.
  2. Macintyre, Jane E. (1992). Dictionary of Inorganic Compounds. CRC Press. p. 2819. ISBN 9780412301209.
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