Bassanite

Bassanite is a calcium sulfate mineral with formula CaSO₄·1/2H₂O or 2CaSO₄·H₂O. In other words it has half a water per CaSO₄ unit hence its synonym calcium sulfate hemihydrate.

Bassanite
Bassanite (30 by 26 mm white mass with some gypsum crystals)
General
Category	Sulfate mineral
Formula (repeating unit)	CaSO4·1/2H2O
Strunz classification	7.CD.45
Crystal system	Monoclinic
Space group	Spheroidal (2) (same H-M symbol)
Unit cell	a = 12.0317 Å, b = 6.9269 Å, c = 12.6712 Å, β = 90.27°; Z = 12
Identification
Color	White
Crystal habit	Microscopic acicular crystals in parallel aggregates, pseudohexagonal
Twinning	Twin plane {101}
Luster	Earthy
Streak	White
Diaphaneity	Semitransparent
Specific gravity	2.69–2.76
Optical properties	Biaxial (+)
Refractive index	nα = 1.550–1.559, nβ = 1.560, nγ = 1.577–1.584
2V angle	10–15°
Alters to	Dehydrates on heating to anhydrite
References	[1][2][3]

Bassanite was first described in 1910 for an occurrence on Mount Vesuvius. It was named for Italian paleontologist Francesco Bassani (1853–1916).[1]

At Vesuvius it occurs as alterations from gypsum within leucite tephrite and as fumarole deposits. It occurs in dry lake beds in California and Australia. It also occurs interlayered with gypsum in caves.[2]

H. Schmidt and coinvestigators reported in 2011 that under dry conditions, the structure is monoclinic with space group C2, but at 75% humidity, the structure is trigonal with space group P3₂21. This reflects the incorporation of additional water of hydration, such that the trigonal form has the formula CaSO₄·0.625H₂O[4]

References

1. Bassanite on Mindat.org
2. Bassanite in the Handbook of Mineralogy
3. Bassanite data on Webmineral
4. Schmidt, Horst; Paschke, Iris; Freyer, Daniela; Voigt, Wolfgang (1 December 2011). "Water channel structure of bassanite at high air humidity: crystal structure of CaSO 4 ·0.625H 2 O". Acta Crystallographica Section B Structural Science. 67 (6): 467–475. doi:10.1107/S0108768111041759.