2,2'-Biquinoline
2,2'-Biquinoline is an organic compound with the formula (C9H6N)2. It is one of several dimers of the bicyclic heterocycle called quinoline. It is prepared by reductive coupling of 2-chloroquinoline.[1] It is a colorimetric indicator for organolithium compounds.[2]
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Other names
2,2'-Biquinolyl; 2-Quinolin-2-ylquinoline; Cuproin | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.003.961 |
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CompTox Dashboard (EPA) |
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Properties | |
C18H12N2 | |
Molar mass | 256.308 g·mol−1 |
Appearance | White solid |
Melting point | 194.5 °C (382.1 °F; 467.6 K) |
Hazards | |
GHS pictograms | |
GHS Signal word | Warning |
H315, H319, H335 | |
P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
References
- Nelson, Todd D.; Crouch, R. David (2004). "Cu, Ni, and Pd Mediated Homocoupling Reactions in Biaryl Syntheses: The Ullmann Reaction". Org. Reactions. 15. doi:10.1002/0471264180.or063.03.
- Watson, Spencer Charles; Eastham, Jerome F. (1967). "Colored Indicators for Simple Direct Titration of Magnesium and Lithium Reagents". Journal of Organometallic Chemistry. 9: 165–8. doi:10.1016/S0022-328X(00)92418-5.
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